Publication list (1996-2003):

  • Stability and structure of mono- and dinuclear Cu(II), Ni(II), and Zn(II) complexes of pyrazole and triazole bridged bis-macrocycles.
    M. Raidt, M. Neuburger, Th. A. Kaden, Dalton Trans. 2003, 1292.


  • The dual role of self-assembled monolayers of tetraazamacrocyclic Cu(II) complexes in ascorbate oxidation catalysis.
    K. Stolarczyk, R. Bilewicz, L. Siegfried, Th. A. Kaden, Inorg. Chim . Acta 2003, 348, 129.


  • Synthesis and complexation properties of ditopic ligands built from a macrocyclic and an open chain chelator moiety
    L. Siegfried, M. Honecker, A. Schlageter, Th. A. Kaden, Dalton Trans. 2003, 3939.


  • Formation and dissociation kinetics of dinuclear metal complexes with pyrazole and triazole bridged bis-macrocycles.
    M. Raidt, L. Siegfried, Th. A. Kaden, Dalton Trans. 2003, 4493.


  • Phosphate and phosphonate ester hydrolysis promoted by dinuclear metal complexes.
    Ch. Vichard, Th. A. Kaden, Inorg. Chim . Acta 2002, 337, 173


  • Central vs. peripheral Ag(I) coordination in NS3-open chain and cage ligands.
    J. Baumeister, R. Alberto, K. Ortner, B. Spingler, P.A. Schubiger, Th. A. Kaden, J. Chem. Soc., Dalton Trans. 2002, 4143.


  • Complexes of a bis(tetradentate) compartemental pyrazolate ligand: solution studies and solid state structures.
    L. Siegfried, Th. A. Kaden, F. Meyer, P Kircher, H. Pritzkow, J. Chem. Soc., Dalton Trans. 2001, 2310.


  • Kinetics and mechanism of the Cu2+induced hydrolysis of nitrile groups in the side chain of tetraazamacrocycles. Models for nitrilases.
    L. Siegfried, R. Kowallick, Th. A. Kaden, Supramol. Chem. 2001, 13, 2310.

  • pH-metric and NMR studies of the complexation of Zn2+, Cd2+, and Pb2+ with diazacrown ethers having dangling phosphonate groups.
    M. Peters, L. Siegfried, Th. A. Kaden, J. Chem. Soc., Dalton Trans. 2000, 4664.

  • Determination of pKa values of 4-phosphonato-2,2':6',6"-terpyridine and its Ruthenium(II) based photosensitizer by NMR potentiometric and spectrophotometric methods.
    M. K. Nezeeruddin, S.M. Zakeeruddin, R. Humphry-Baker, Th.A. Kaden, M. Grätzel, Inorg. Chemistry 2000, 39, 4542.


  • Reactivity and function of macrocyclic metal complexes,
    Th.A. Kaden, Chimia 2000, 54, 574.


  • Labelling monoclonal antibodies with metal complexes: a challenge for coordination chemists.
    Th.A. Kaden, Chimia 2000, 54, 46.


  • Coordination chemical aspects of In3+, Y3+, Ga3+, Cu2+, and Ag+ metal complexes of mono- and bifunctional chelators.
    A. Heppeler, E. Jermann, T. Gyr, R.M. Dyson, G. Ruser, M. Henning, M. Neuburger, M. Neuburger-Zehnder, Th. Kaden, H.R. Maecke
    in "Technetium, rhenium and other metals in chemistry and nuclear medicine" (Ed. M. Nicolini, U. Mazzi), SGE Editoriali, Padova 1999, p. 65


  • Modified electrode surfaces for catalytic reduction of carbon dioxide.
    A. Jarzebinska, P. Rowinski, I. Zawisa, R. Bilewicz, L. Siegfried, Th.A. Kaden Anal. Chim. Acta. 1999, 396, 1


  • Metal complexes of macrocyclic ligands.
    Th. A. Kaden, Chimia 1999, 53, 208


  • Unexpected polymeric string formation between Ag(I) and a homoleptic thioether cage: Synthesis and crystal structure of [R,R'-S6tricosane] and [Ag(R,R'-S6hexacosane)(tos).
    R. Alberto, D. Angst, U. Abram, K. Ortner, Th. A. Kaden, A.P. Schubiger,J. Chem. Soc., Chem. Commun. 1999, 1513.


  • Dinuclear metal complexes of bis-macrocycles.
    Th.A. Kaden, Coord. Chem. Rev. 1999, 192, 371.


  • A fully automated pH-NMR titration set-up for protonation studies.
    M. Peters, L. Siegfried, Th. A. Kaden, J. Chem. Soc., Dalton Trans. 1999, 1603


  • Potentiometric, spectrophotometric, and ES-mass spectroscopic studies of the formation of binary and ternary species between Cu2+, a pyrazole bridged N2S-bis-macrocycle and exogenous ligands.
    H. Weller, Th.A. Kaden, G. Hopfgartner, Polyhedron, 1998, 17, 4543


  • Unexpected N-configurations in a Ni2+ complex of a mono-N-functionalized macro-cycle.
    C. Schmid, M. Neuburger, M. Zehnder, Th.A. Kaden, Th. Hübner, Polyhedron, 1998, 17, 4065


  • Structural and 99mTc-NMR investigations of complexes wit fac-[Tc(CO)3]+ moieties and macrocyclic thioethers of various ring sizes: Synthesis and X-ray structure of the complexes fac-[Tc(9-ane-S3)CO)3]Br, fac-[Tc2(tosylate)2(18-ane-S6)CO)6] and fac-[Tc2(20-ane-S6-OH)CO)6](tosylate)2.
    R. Schibli, R. Alberto, U. Abram, S. Abram, A. Egli, P.A. Schubiger, Th. A. Kaden, Inorg. Chemistry 1998, 37, 3509.


  • Metal complexes with macrocyclic ligands. Part XLVII. Copper(II) and Nickel(II) complexes of trans-difunctionalized tetraaza macrocycles.
    A. Comparone, Th. A. Kaden, Helv. Chim. Acta 1998, 79, 1765


  • A novel organometallic aqua complex of technetium for the labeling of biomolecules: Synthesis of [(Tc-99m(OH2)3(CO)3)]+ from 99mTcO4¯ in aqueous solution and its reaction with a bifunctional ligand .
    R. Alberto, R. Schibli, A. Egli, P.A. Schubiger, U. Abram, Th. A. Kaden, J. Amer. Chem. Soc. 1998, 120, 7987.


  • Steps towards [(C5Me5)TcO3]: Novel synthesis of [(C5Me5)TcO3] from [(Tc(_-OH)3-(CO)3)4] and oxidation of [(C5Me5)M(CO)3] (M = Tc, Re) with Br2.
    R. Alberto, R. Schibli, A. Egli, U. Abram, S. Abram, Th. A. Kaden, P.A. Schubiger, Polyhedron 1998, 17, 1133


  • Effects of ligand structure on the adsorption of nickel tetraazamacrocyclic complexes and electrocatalytic CO2 reduction.
    K. Bujno, R. Bilewicz, L. Siegfried, Th. A. Kaden, J. Electroanalyt. Chem. 1998, 445, 47


  • Application of technetium and rhenium carbonyl chemistry to nuclear medicine. Preparation of (NH4)2[TcCl3(CO)3] from (NBu4)[TcO4] and structure of (NH4)2[Tc2(m-Cl)3(CO)6]; structure of the model complexes (NEt4)[Re2(m-OEt)2(m-OAc)(CO)6] [ReBr(-CH2S(CH2)2Cl)2(CO)3].
    R. Alberto, R. Schibli, D. Angst, P.A. Schubiger, U. Abram, Th. Kaden, Trans. Metal Chem. 1997, 22, 597


  • Binucleating ligand structural effects on (m-peroxo)- and bis(m-oxo)dicopper complex formation and decay: competition between arene hydroxylation and aliphatic C-H bond activation.
    S. Mahapatra, S. Kaderli, A. Llobet, Y.-M. Neuhold, T. Palanché, J. Halfen, V. Young, Th. Kaden, L. Que, A. Zuberbühler, W. Tolman. Inorg. Chem. 1997, 36, 6343


  • Metal complexes with macrocyclic ligands. Part XLVI.Synthesis and structure of dinuclear metal complexes of bis-macrocycles having a pyrazole bridging unit.
    H. Weller, L. Siegfried, M. Neuburger, M. Zehnder, Th. A. Kaden, Helv. Chim. Acta 1997, 78, 2315


  • Metal complexes with macrocyclic ligands. Part XLV. Axial coordination tendency in reinforced tetraazamacrocyclic complexes.
    R. Kowallik, M. Neuburger, M. Zehnder, Th. A. Kaden, Helv. Chim. Acta 1997, 78, 948


  • Metal complexes with macrocyclic ligands. Part XLIV. Kinetics of the Cu2+ incorporation into a macrocyclic ligand conjugated to proteins: model studies for the "post-labelling" technique. M. Manzetti, L. Macko, M. Neuburger-Zehnder, Th. A. Kaden, Helv. Chim. Acta 1997, 80, 934


  • Metal complexes with macrocyclic ligands. Part XLIII. Tetraazamacrocyclic Ni(II) and Cu(II) complexes with aliphatic methylthio and methoxy-substituted pendant chains.
    C. Schmid, M. Neuburger, M. Zehnder, Th. A. Kaden, K. Bujno, R. Bilewicz, Helv. Chim. Acta 1997, 80, 241


  • Electroreduction of CO2 catalyzed by Ni(II) tetraazamacrocyclic complexes.-Reasons for poisoning of the catalytic surface.
    K. Bujno, R. Bilewicz, L. Siegfried, Th. A. Kaden, Electrochim. Acta 1997, 42, 1201


  • Ten-membered rings or larger with one or more nitrogen atoms.
    Th. A. Kaden in Comprehensive Heterocyclic Chemistr II ( Ed. G. R. Newcome), Elsevier, Oxford 1996, Vol. 9, p. 789.


  • Metal complexes with macrocyclic ligands, XLII. Tetraazamacrocyclic Nickel(II) complexes with a methylthio or a methoxy pendant chain as model for cofactor F430.
    C. Schmid, Ch. Kempf, A. Taubert, M. Neuburger, M. Zehnder, Th. A. Kaden, K. Bujno, R. Bilewicz, Helv. Chim. Acta 1996, 79, 1011


  • Electrochemical behaviour of isomers of a tetraazamacrocyclic Ni(II) complex in solutions saturated with argon, CO and CO2.
    K. Bujno, R. Bilewicz, L. Siegfried, Th. A. Kaden, J. Electroanal. Chem. 1996, 407, 131


  • Silver(I) complexes of the derivatized crown thioether ligands 3,6,9,12,15,18-hexa-thianonadecanol and 3,6,9,13,16,19-hexathiaicosanol. Determination of the stability constants and the crystal structures of [Ag(19-aneS6-OH)](CF3SO3) and [Ag(20-aneS6-OH)](BF4).
    R. Alberto, W. Nef, A. Smith. T.A. Kaden, M. Neuburger, M. Zehnder, A. Frey, U. Abram, P.A. Schubiger, Inorg. Chem. 1996, 35, 3420


  • Kinetics and mechanism of Cu2+ incorporation into homo- and heteroditopic bis-macrocycles studied by the stopped-flow/photodiode-array technique.
    L. Siegfried, A. Urfer, Th. A. Kaden, Inorg. Chim. Acta 1996, 251, 177.


  • H+ and CN¯ induced dissociation of Ni(II)-complexes with tetra-N-substituted 1,4,8,11-tetraazacyclotetradecanes.
    M.R. Oberholzer, L. Siegfried, Th. A. Kaden, Inorg. Chim. Acta 1996, 264, 41.


  • A simple single-step synthesis of [(99Tc3H3)(CO)12] from [99TcO4]¯ and its X-ray crystal structure. Application to the production of no-carrier added [(188Re3H3)(CO)12].
    R. Alberto, R. Schibli, P. A. Schubiger, U. Abram, R. Hübener, H. Berke, Th.A. Kaden, J.Chem. Soc., Chem. Commun. 1996, 1291


  • Reactions with the technetium and rhenium carbonyl complexes (NEt4)2[MX3(CO)3]. Synthesis and structure of [Tc(CN-tBut)3(CO)3](NO3) and (NEt4)[Tc2(m-SCH2-CH2- OH)3(CO)6].
    R. Alberto, R. Schibli, P. A. Schubiger, U. Abram, Th.A. Kaden, Polyhedron 1996, 15, 1079


  • Metal complexes with macrocyclic ligands, XLI. Nickel(II) and copper(II) complexes of mono-N-functionalized dithiadiazamacrocycles.
    E. Hörmann, P. C. Riesen, M. Neuburger, M. Zehnder, Th.A. Kaden, Helv. Chim. Acta 1996, 79, 235