Some Publications

BaI2(thf)5 BaI2(thf)3 BaI2(OH2)(OC3H6)
K. M. Fromm, Angew. Chem.1997, 109 (24), 2876 Angew. Chem. Int. Ed. Engl. 1997, 36 (24), 2799-2801

Ca7I6(OH)8(thf)12; Chem. Comm. 1999, 17, 1659-1660


Published:
  1. "Synthesis and Crystal Structure of meso-(1,2,3-Tricyclohexyltriphosphane-1,3-diyl)zirconocene (IV), Cp2Zr(PCy-PCy-PCy) (Cp = h5-C5H5; Cy = C6H11)"

    Katharina Fromm, Gerhard Baum, Evamarie Hey-Hawkins, Z. anorg. allg. Chem. 1992, 615, 35-38

  2. "Reaction of Cyclopentadienyl Substituted Molybdenum (V) Tetrachlorides with LiPH(2,4,6-But3C6H2) and KPPh2(Dioxane)2. Crystal Structures of [Cp°Mo(μ-Cl)2]2 and [Cp°2Mo2(μ-Cl)3(m-PPh2)] (Cp° = C5Me4Et)"

    Katharina Fromm, Evamarie Hey-Hawkins, Z. anorg. allg. Chem. 1993, 619, 261-270

  3. "Mixed-Valence Dinuclear Molybdenum Complexes: Synthesis and Molecular Structure of (Cp°Mo)2(μ-Cl)n(μ-PPh2)3-n (n = 1,0 ; Cp° = h5-C5Me4Et)"

    Katharina Fromm, Evamarie Hey-Hawkins, Polyhedron 1995, 14, 2027-2035

  4. "Synthesis and Molecular Structures of Molybdenum Complexes with Phosphido, Diphosphanyl and Diphosphene Ligands"

    Katharina Fromm, Evamarie Hey-Hawkins, Polyhedron 1995, 14, 2825-2834

  5. "Synthesis and Molecular Structures of the Molybdenum (II) Complexes MoCl2(PMe3)2 and [Mo(μ-PPh2)(PPh2)(PMe3)]2"

    Katharina Fromm, Evamarie Hey-Hawkins, Monika Plaikner, Z. Naturforsch. 1995, 506, 894-898

  6. "Zintl Anions as Starting Compounds for the Synthesis of Polynuclear Transition Metal Complexes"

    Reinhard Ahlrichs, Dieter Fenske, Katharina Fromm, Harald Krautscheid, Ulrike Krautscheid, Oliver Treutler, Chem. Eur. J. 1996, 2, 238-244

  7. "New alkali and alkaline earth metal halide complexes"

    K. Fromm, Book of Abstracts, 211th ACS National Meeting, New Orleans, LA, 1996

  8. "Organometallic Tantalum Complexes with Phosphine, Phosphanido and Phosphinidene Ligands, Synthesis and Crystal Structures of [Cp’TaCl4{PH2(2,4,-Pri3C6H2)}], [Cp’Ta(μ-PPh2)(PPh2)]2×C7H8 and [Cp’TaCl{μ-P(2,4,6.Pri3C6H2)}]× C7H8 (Cp’ = C5H4Me)"

    Katharina M. Fromm, Steffen Blaurock, Svea Jelonek, Evamarie Hey-Hawkins, Ghasan A. Abdul Hadi, Polyhedron 1997, 16, 721-731

  9. "Structural Evolution from the Solid State to the Molecule for BaI2 : Synthesis and Crystal Structures of [BaI2(μ-OH2)2]3-dim, [BaI2(μ -OH2)(OC3H6)]2-dim , [BaI2(thf)3]1-dim and [BaI2(thf)5]×THF"

    Katharina M. Fromm, Angew. Chem. 1997, 109, 24, 2876-2878, Angew. Chem. Int. Ed. Engl. 1997, 36, 24, 2799-2801

  10. "Reducible Nanoscale Molecular Rods Based on Diacetylene-linked Poly(phenylthio)-substituted Benzenes"

    Katharina M. Fromm, Marcel Mayor, Jean-Marie Lehn, Dieter Fenske, Angew. Chem. Int. Ed. Engl. 1997, 36, 21, 2370-2372

  11. "Toposelective Self-Assembly of [2x2] Grid-type Inorganic Arrays Containing Different Octahedral Metallic Centres"

    Katharina M. Fromm, Dario M. Bassani, Jean-Marie Lehn, Dieter Fenske, Angew. Chem. Int. Ed. Engl. 1998, 17, 2364-2367

  12. "Synthesis and crystal structure of Li[{Ca73-OH)8 (thf)12}2I]× 3THF, a unique H-bound dimer of a Ca7-cluster on the way to sol-gels"

    Katharina M. Fromm, Chem. Comm. 1999, 17, 1659-1660

  13. "Similar Coordination – Different Dimensionality: Synthesis, Single Crystal Structures and Theoretical Studies of {[Ca(H2O)2L4]I2}(1: L = CH3COOC2H5; 2: L = OC4H8)"

    Katharina M. Fromm, G. Bernardinelli, H. Goesmann, M.-J. Mayor-Lopez, J. Weber, Z. Anorg. Allg. Chem. 2000, 7, 1685-1691

  14. "Multiple Expression of Molecular Information: Enforced Generation of Different Supramolecular Inorganic Architectures by Processing of the Same Ligand Information Through Specific Coordination Algorithms"

    Katharina M. Fromm, Daniel P. Funeriu, Jean-Marie Lehn, Dieter Fenske, Chem. Eur. J., 2000, 6, 2103-2111

  15. "H-bridged polymer structures of different dimensionality: Synthesis and crystal structure of [Ca(DME)n(OH2)m]I2(DME)x, (1: n = 3,m = 3, x = 1; 2: n = 2, m = 4, x = 0)"

    Katharina M. Fromm, G. Bernardinelli, H. Goesmann, Polyhedron, 2000, 19, 1783-1789

  16. "On the way to sol-gels: An analysis of the intra- and intermolecular hydrogen bonding in [Ba(OH)I(H2O)4]"

    Katharina M. Fromm, H. Goesmann, Acta Cryst. Sect. C, 2000, 56, 1179-1180

  17. "Synthesis and crystal structure of [IBa(OtBu)4{Li(thf)}4(OH)]: a mixed ligand heterometallic cluster with an unusual low coordination number for barium"

    Katharina M. Fromm, E. D. Gueneau, H. Goesmann, Chem. Commun. 2000, 2187-2188

  18. "Electron transfer through molecular bridges between reducible pentakis(thiophenyl)benzenes"

    M. Mayor, M. Büschel, Katharina M. Fromm, J.-M. Lehn, J. Daub, Chem. Eur. J., 2001, 7, 1266-1272.

  19. "Hydrogen-bonding and metal ion mediated self-assembly of a nanoporous crystal lattice: Synthesis and Crystal Structure of [Fe(bis-glucoryl-bipyridine)3]Br2"

    Katharina M. Fromm, D. G. Kurth, J.-M. Lehn, Eur. J. Inorg. Chem., 2001, 1523-1526

  20. "A Logical Concept of Structure Predictions in Supramolecular Alkaline Earth Metal Halide Polymers formed by Metal Ion Complexation and Hydrogen bonding"

    Katharina M. Fromm, Chem. Eur. J., 2001, 7, 2236-2244

  21. "Synthesis and Crystal Structure of the one-dimensional  polymer Compound {[Ba(OTf)3(thf)3]2[Ba(OTf)3(thf)2]}1-dim (OTf = CF3SO3-) - excerpts from a three-dimensional structure as an access to new materials?"

    Katharina M. Fromm, G. Bernardinelli, Z. Anorg. Allg. Chem., 2001, 627, 1626-1630

  22. "Electron transfer through bridging molecular structures"

    M. Mayor, M. Büschel, K. M. Fromm, J.-M. Lehn, J. Daub, Annals of the New York Academy of Sciences (2002) , Molecular Electronics II, (Proceedings of the International ACS Meeting of Hawaii, USA, December 2000, ISBN 1-57331-410-2).

  23. "Crown ethers as stabilizing ligands for asymmetric coordination: Synthesis, Crystal Structure and Physical Properties of [Na(DB18C6)I(thf)], [Na(DB18C6)I(1,3-dioxolane)] and [Na(DB24C8)]I  (DB18C6 = Dibenzo-18-crown-6, DB24C8 = Dibenzo-24-crown-8)"

    Katharina M. Fromm, E. D. Gueneau, J.-P. Rivera, G. Bernardinelli, H. Goesmann, Z. Anorg. Allg. Chem., 2002, 628, 171-178

  24. "Ionic or covalent? Can some first aspects to the answer be derived from the solid state structures of alkaline earth metal halide adducts?"

    Katharina M. Fromm, Cryst. Eng. Comm., 2002, 4(57), 318-322

  25. "Recent advances in the chemistry of clusters and inorganic polymers of alkali and alkaline earth metal compounds"

    Katharina M. Fromm, Chimia, 2002, 56(12), 676-680.

  26. "Synthesis and structural analysis of the polymetallated alkali calixarenes [M4(p-tert-butylcalix[4]arene-4H)(thf)x]2·n THF (M = Li, K; n = 1 or 6; x = 4 or 5) and [Li2(p-tert-butylcalix[4]arene-2H)(H2O)(μ-H2O)(thf)]·3THF"

    Katharina M. Fromm, E. D. Gueneau, H. Goesmann, Chem. Eur. J. 2003, 9(2), 509-514.

  27. "One-dimensional water” and “one-dimensional acid”: Synthesis and the unique crystal structure of 1∞[(H2O)(DB18C6)(μ-H2O)2/2]1∞[(H3O)(DB18C6)(μ-H2O)2/2]I3 (DB18C6 = dibenzo-18-crown-6)"

    Katharina M. Fromm, E. D. Gueneau, H. Goesmann, C. Bochet, Z. Anorg. Allg. Chem., 2003, 629(4), 597-600.

  28. "Understanding the Formation of New Clusters of Alkali and Alkaline Earth Metals: a New Synthetic Approach, Single Crystal Structures and Theoretical Calculations"

    Katharina M. Fromm, E. D. Gueneau, G. Bernardinelli, H. Goesmann, J. Weber, M.-J. Mayor-López, P. Boulet, H. Chermette, J. Am. Chem. Soc., 2003, 125(12), 3593-3604.

  29. "Oxygen Donor Stabilized Alkaline Earth Metal Iodides"

    Katharina M. Fromm, Chimia, 2003, 57(4), 175-178.

  30. "Polar molecular precursors for alkali and alkaline earth metal clusters and low-dimensional polymer structures: the solid state structures of [CaI(dme)3]I, and cis-[SrI2(diglyme)2] (dme = CH3OC2H4OCH3; diglyme = CH3(OC2H4)2OCH3)"

    Katharina M. Fromm, W. Maudez, Eur. J. Inorg. Chem. 2003, 18, 3440-3444

  31. "Structural relationship of two coordination polymers of Cu(I) with the ligand ethanediyl bis(isonicotinate)"

    Adeline Y. Robin, Katharina M. Fromm, Helmut Goesmann, Gérald Bernardinelli, Cryst. Eng. Comm., 2003, 5(71), 405–410

  32. " .∞1 [M(μ-O2C-C6H4-CO2)(NH3)2] (M = Cu, Cd; O2C-C6H4-CO2 = benzene-1,4-dicarboxylate, terephthalate): 1D coordination polymers with strong inter-chain hydrogen bonding"

    B. Paul, B. Zimmermann, K. M. Fromm, C. Janiak, Z. Anorg. Allg. Chem., 2004, 630, 1650-1654.

  33. "Molecular paneling of rac-1,1’-bi-2-naphthol/yate (BINOL/BINOLAT): hydrogen-bonded assembly of [M(NH3)4 or 6]2+ complexes (M ~ Ni, Zn, Cd) in cavities of {[BINOLAT]2-(BINOL)2}-strands"

    B. Paul, C. Näther, B. Walfort, K.M. Fromm, B. Zimmermann, H. Lang, C. Janiak, Cryst. Eng. Comm. 2004, 6(51), 293-297

  34. "Structural Diversity of coordination polymers with the ligand ethanediyl bis(isonicotinate): Part 4. Coordination compounds of Ag(I) and dependency of the co-crystallizing water molecules"

    K. M. Fromm, A. Robin, M. Meuwly, H. Goesmann, G. Bernardinelli, Cryst. Eng. Comm. 2004, 6(60), 336–343

  35. "Recent Advances in the Chemistry of “Clusters” and Coordination Polymers of Alkali, Alkaline Earth Metal and Group 11 Compounds"

    K. M. Fromm, E. D. Gueneau, A. Y. Robin, W. Maudez, J. Sague, R. Bergougnant, Z. Anorg. Allg. Chem., 2005, 631, 1724-1740

  36. "Chiral S-1,1’-bi-2-naphthol (S-BINOL) as a synthon for supramolecular hydrogen-bonded {(S-BINOLATn-)(S-BINOL)n} -strands with naphthyl-paneled cavities or channels for a Cd(NH3)4-fragment (n = 2) or [Ag(NH3)2]+ (n = 1)."

    B. Paul, C. Näther, K. M. Fromm, C. Janiak, Cryst. Eng. Comm., 2005, 7(51), 309–319

  37. "Hooked on Calix[8]arenes: a (H2O)10-cluster with an unprecedented structure"

    R. D. Bergougnant, A. Y. Robin, K. M. Fromm, Cryst. Growth & Design, 2005, 5(5), 1691-1694

  38. "Concomitant crystallization of two polymorphs – a ring and a helix: Concentration effect on supramolecular polymorphism"

    J. L. Sagué Doimeadios, A. Y. Robin, K. M. Fromm, Chem. Commun., 2005, 36, 4548-4550

  39. "Water trapped in dibenzo-18-crown-6: theoretical and spectroscopic (IR, Raman) studies"

    M. Dulak, R. Bergougnant, K. M. Fromm, H. R. Hagemann, A. Y. Robin, T. A. Wesolowski, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy 2005, 64, 532-548

  40. "[Ag(isonicotinamide)2NO3]2 - a Stable Form of Silver Nitrate"

    T. Dorn, K. M. Fromm, C. Janiak, Aust. J. Chem. 2006, 59, 22-25

  41. "On the coordination behaviour of NO3- in coordination compounds with Ag+: Part 1. Solubility effect on the formation of coordination polymer networks between AgNO3 and L (L = ethanediyl bis(isonicotinate) as a function of solvent"

    A. Y. Robin, J. L. Sagué, K. M. Fromm, Cryst. Eng. Comm. 2006, 8, 403-416

  42. "Di-Benzo-18-Crown-6 and its derivatives as ligands in the search for ion channels"

    K. M. Fromm, R. D. Bergougnant, A. Y. Robin, Z. Anorg. Allg. Chem. 2006, 632, 828-836

  43. "Substitution reactions on Alkaline Earth Metal Iodides: A large anionic Sr12-aggregate [{Sr6(O)(μ3-I)(I)2(OtBu)7(thf)3}2(μ-I)]-"

    W. Maudez, T. Vig-Slenters, L. Mirolo, A. Fleury, K. M. Fromm, Main Group Chemistry 2006, in the press

  44. "Film-Forming Polymers Containing in the Main-Chain Dibenzo Crown Ethers with Aliphatic (C10-C16), Aliphatic-Aromatic, or Oxyindole Spacers

    Mikhail G. Zolotukhin, G. Hernández, María del Carmen, Ana Maria Lopez, Loudmila Fomine, Gerardo Cedillo, Aurora Nogales, Tiberio Ezquerra, Daniel Rueda, Howard M. Colquhoun, Katharina M. Fromm, Alberto Ruiz-Treviño, Moonhor Ree, Macromolecules, 2006, in press

  45. Invited Reviews:

  46. "Coordination Compounds"

    K. M. Fromm, Kirk-Othmer Encyclopedia of Chemical Technology, Copyright © 2003 by John Wiley & Sons, Inc.

  47. "Structures of Alkali and Alkaline Earth Metal Clusters with Oxygen Donor Ligands"

    K. M. Fromm, E. D. Gueneau, Polyhedron 2004, 23(9), 1479-1504.

  48. "Coordination Polymer Networks with O- and N-Donors: What they are, why and how they are made"

    A. Y. Robin, K. M. Fromm, Coord. Chem. Rev. 2006, in press